The Cross Product between two vectors will yield a vector that is orthogonal to the BOTH of them. So for example if I get a vector along the X axis and CROSS PRODUCT it with a vector along the Y axis, then I will get a vector along the positive/negative Z axis (depending on whether it's X x Y or Y x X).
So suppose I have 3 vectors a, b and c such that a x b = c.
I can safely say that a.c = 0 and b.c = 0 as well since a and b are both orthogonal to c.
In the diagram below, the red line is the result of the cross product (could point the other way around but either way, orthogonality is preserved).
So we have w x u = v - w (I have shown it in red in the diagram below):
Let the intersections of the 3 black lines (so where I drew the right angle symbol) be O.
By definition of the cross product, we have the plane containing WOU being perpendicular to the plane containing WOV. But vector V lies on plane WOV and vector U lies on WOU, so the two vectors are perpendicular.
So U is perpendicular to V, so therefore U . V = 0.
Really, I should have drawn the parallelpipid to be a rectangular prism (which is a special case of a parallelpipid where all 3 vectors are orthogonal to each other such that they make 'their own XYZ plane' if you get what I mean).