Alternatively, you can construct the vector z-w (using vector addition and subtraction), and then use basic Euclidean Geometry to prove that Arg(z-w) is 15 degrees (or pi/12)
1. Draw the usual parallelogram, including z-w.
2. Notice that Arg(w) = 2pi/3, which means that the bigger angle of the parallelogram is simply 2pi/3 + pi/2 = 7pi/6
3. We divide this by 2 because the vector z-w bisects this big angle, giving us 7pi/12
4. Arg (z-w) is the 'excess' of this after taking away 90 degrees (pi/2), leaving us Arg (z-w) = pi/12
Sorry if this is a bit ambiguous. I have included a diagram which may or may not help.