回复: BCS theory
These pairs are formed when one electron distort the positively charges ions in the lattice to move inwards towards the electron. This creates a region of increased positive charge density. Due to the elasticity of the lattice, the region propagates throughout the lattice as a wave. The second electron passing through the lattice is attracted to this moving region, and is “swept” along by the lattice wave created by the first electron, essentially “pairing” up into Cooper pairs. This is called electron-lattice-electron interaction.
BCS theory was developed in 1957 by John Bardeen, Leon Cooper, and John Schrieffer in order to explain why superconductivity occurs. BCS theory describes the formation of electron pairs, or Cooper pairs, moving through the crystal lattice unimpeded and bypassing the obstacles in the crystal lattice which were responsible for electrical resistance. Bardeen, Cooper, and Schrieffer knew electrons normally repel each other and decided there must be some overwhelming attractive force between electrons of a Cooper pair. This attractive force was suggested to be phonons; packets of sound energy also acting as force particles. The process that occurs between Cooper pairs and the crystal lattice is called the electron-lattice-electron interaction.
Essentially, Cooper pairs form when one electron passes through a lattice and as a result distorts the lattice of positively charged ions inwards towards the electron, creating a region of increased positive charge density. This electron is said to release a phonon into the lattice to pull the lattice closer. Due to the elasticity of the lattice, this region is propagates through the lattice as a wave. The phonon is then retrieved by the second electron which is attracted into this moving region of increased positive charge density, and the second electron is effectively swept along by the lattice wave created by the first electron. The second electron pairs-up with the first electron and also transfers the retrieved phonon to the leading electron to be reused to distort another section of the lattice. Thus by pairing off two by two, the electrons pass smoothly through the lattice without losing energy.
Hence BCS theory explains superconductivity and the absence of electrical resistance (below the critical temperature) through Cooper pairs and electron-lattice-electron interaction.
The lone electron also gains passage but if I remember correctly, the pair produces a bigger positive charge density, allowing electrons to flow through more easily -> less resistance.
These are from my notes, haven't been able to learn it completely yet. Please point out if theres any mistakes.