Rules for Significant Figures:
1. All non-zero digits are significant.
2. The first non-zero digit is the first significant figure.
3. All zeros after the first significant figure are also significant.
4. Trailing zeros may or may not be significant.
For example:
The population of Australia is (something like) 21,376,842. Rounded off to 3 sig figs this would be 21,300,000. We need the extra zeros to hold the place values. This number is clearly an approximation, so in this case the zeros at the end are not significant.
The width of a football field is 70 m (exactly). So in this case the zero at the end IS significant because it hasn't been rounded off yet.
Significant figures are really easy if you get your head around scientific notation.
For example, write 0.00004562 in scientific notation, correct to 2 significant figures.
First do the sci notation: 4.562 x 10-5
See how the first 5 digits, the zeros, are not significant!
Then round off: 4.6 x 10-5
Hope this helps